Has Cadmium Selenide Found Its Killer App?
June 3rd, 2010During Display Week, in Room 3017 at the Sheraton Seattle Hotel, Peter Brody of Advantech showed a 4-inch, 100 dpi, QVGA OLED with a cadmium selenide (CdSe) TFT backplane fabricated by evaporating TFT films through a shadow masks rather than using. photolithography.

Ken Werner
Senior Analyst and Editor
Brody, who is often credited with building the world’s first active-matrix LCD in 1972, says this approach can produce uniform power transistors for driving AMOLED color sub-pixels over large areas. "But," says Brody, "CdSe is only half the answer. The other half is that it lends itself to evaporative deposition, so we can use a very simple and inexpensive manufacturing technology."
In a presentation prepared by Advantech Global (Brody’s company) for a well-known Chinese TV manufacturer, Brody compared the costs of producing a 17-inch display panel with current a-Si LCD processes on a Gen 5 fab, LTPS OLED processes, and with three iterations of Advantech’s AMAX miniLine in-line manufacturing system. He concludes that the simple evaporative CdSe process, which requires a relatively small capital investment, is capable of delivering OLED’s well-appreciated image-quality advantages at a cost that is actually less than LCD.
The 4-inch demonstrator Advantech showed in Seattle was made in a single deposition system, but the company is currently installing a multi-million-dollar in-line fabrication system in Pittsburgh, in which each circuit level is deposited in a dedicated chamber, with all chambers operating simultaneously. The system will be capable of a finished-circuit TACT time of 5 minutes, Brody says, with 2 minutes possible in later generations.

Advantech made the demonstrator’s CdSe backplane. OLED processing, including the tri-color emitters, was performed by BOE in Beijing. Each pixel switch in the demonstrator consists of two TFTs, a storage capacitor and an output terminal, with each sub-pixel measuring 83×250 microns.
Back in the ’70s, CdSe’s potential was appreciated, but many people were concerned with the toxicity of Cadmium. Brody says CdSe is safe, and makes the following points:
- Cd is ionically bound to Se and can only be separated from the Se with strong acids.
- If display products containing CdSe backplanes are disposed of in the ground, Cd does not leach out and therefore does not pose an environmental hazard.
- The weight of the cadmium in a typical backplane will be on the order of 1.6 x 10-7 gm/cm2, or less than 1 part in 106 of total weight, which is well below the European requirement of 1 part in 104.
- The average daily human intake of unbound Cd in food is 10 to 25 micrograms, equivalent, says Brody, "to eating about 100 cm2 of our backplanes!"
After years of struggle, it turned out that 3- to 4-inch-class WVGA AMOLEDs were the killer app that pushed PenTile Matrix technology over the top. In a similar way, could it be that the well-documented problems with AMOLED backplane complexity, stability, uniformity, and scalability will provide CdSe with its long-awaited opportunity? We will be tracking the ongoing developments at Advantech with great interest.











